Fabrication of novel TiO2 nanoparticles/Mn(III) salen doped carbon paste electrode: application as electrochemical sensor for the determination of hydrazine in the presence of phenol

Mahmoudi Moghaddam, H and Beitollahi, H and Tajik, S and Sheikhshoaie, I and Biparva, P (2015) Fabrication of novel TiO2 nanoparticles/Mn(III) salen doped carbon paste electrode: application as electrochemical sensor for the determination of hydrazine in the presence of phenol. Environ Monit Assess, 187 (7). p. 407.

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Abstract

Hydrazine and phenol are two important environmental pollutants. In this work, an electrochemical sensor for the selective and sensitive detection of hydrazine in presence of phenol was developed by the bulk modification of carbon paste electrode (CPE) with TiO2 nanoparticles and Mn(III) salen. Large peak separation, good sensitivity, and stability allow this modified electrode to analyze hydrazine individually and simultaneously along with phenol. Applying square wave voltammetry (SWV), a linear dynamic range of 3 × 10(-8)-4.0 × 10(-4) M with detection limit of 10.0 nM was obtained for hydrazine. Finally, the proposed method was applied to the determination of hydrazine and phenol in some real samples.

Item Type: Article
Subjects: R Medicine > RA Public aspects of medicine > RA0421 Public health. Hygiene. Preventive Medicine
Depositing User: azam bazrafshan bazrafshan
Date Deposited: 02 Jan 2016 07:02
Last Modified: 02 Jan 2016 07:02
URI: http://eprints.kmu.ac.ir/id/eprint/24055

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